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2-Azabicyclo[2.2.1]hept-5-en-3-one: Chemical Profile of a Versatile Synthetic Building Block and its Impact on the Development of Therapeutics. earth abundant transition metal catalysis. Sarah Cooper is an author and speaker. Conjugate Reduction of α,β-Unsaturated Carbonyl and Carboxyl Compounds with Poly(methylhydrosiloxane) Catalyzed by a Silica-Supported Compact Phosphane-Copper Complex. 3
Regioselective and Stereospecific Copper-Catalyzed Deoxygenation of Epoxides to Alkenes. heterocycles. 2. Ein maskiertes Kupferhydrid als Katalysator für die Carbonylhydrosilylierung in wässrigen Lösungen. A brief review of state-of-the art is reported on metal hydrides. Copper Hydride-Catalyzed Conjugate Reduction-Aldol Addition Domino Reaction of
Toward ideal carbon dioxide functionalization. (P
Adam P. Sobaczynski, Tobias Bauer, and Rhett Kempe . Recent review papers provide far more detail on complex hydrides. Synthesis of a Room-Temperature-Stable Dimeric Copper(I) Hydride. ) (L
Lewis Base-Catalyzed Enantioselective Conjugate Reduction of β,β-Disubstituted α,β-Unsaturated Ketones with Trichlorosilane: E/Z-Isomerization, Regioselectivity, and Synthetic Applications. (H)
Domino Reactions Involving Catalytic Enantioselective Conjugate Additions. Holger Braunschweig, Alexander Damme, Christian Hörl, Thomas Kupfer, and Johannes Wahler . Electron-Deficient Diphosphines: The Impact of DIFLUORPHOS in Asymmetric Catalysis. Luis Aldea, José M. Fraile, Héctor García-Marín, José I. García, Clara I. Herrerías, José A. Mayoral, Ignacio Pérez. L. Petitjean, T. M. de Winter, P. V. Petrovic, P. Coish, J. Hitce, M. Moreau, T. Bordier, H. C. Erythropel, P. T. Anastas. Van Hoveln, S. C. Schmid, M. Tretbar, C. T. Buttke, J. M. Schomaker. Yu-Ting He, Yang-Jie Mao, Hong-Yan Hao, Zhen-Yuan Xu, Shao-Jie Lou. Chuan-Jin Hou, Wei-Lei Guo, Xiang-Ping Hu, Jun Deng, Zhuo Zheng. Ph
A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B. Jason G. Taylor and Carlos Roque D. Correia . Study of High-Power Ultrasound-Assisted Processes Using Copper-Containing Precursors in Aqueous Media. Synthesis and reactivity of furoquinolines bearing an external methylene-bond: access to reduced and spirocyclic structures. Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids. 1,4-Addition of aryl boronic acids to α,β-unsaturated ketones catalyzed by a CCC–NHC pincer rhodium complex. Triphosphine-Ligated Copper Hydrides for CO2 Hydrogenation: Structure, Reactivity, and Thermodynamic Studies. H
Balancing C=C Functionalization and C=O Reduction in Cu−H Catalysis. Wei-Lei Guo, Chuan-Jin Hou, Zheng-Chao Duan, Xiang-Ping Hu. Dawei Wang, Xiaoli Yu, Xiang Xu, Bingyang Ge, Xiaoli Wang, Yaxuan Zhang. Ting Pan, Pan Shi, Bo Chen, Da-Gang Zhou, Ya-Li Zeng, Wen-Dao Chu, Long He, Quan-Zhong Liu. Ling Liu, Xiaonian Li, Hong Dong, Chuan Wu. Jinyue Ding, Jack Chang Hung Lee, and Dennis G. Hall . Mechanistic studies and catalytic cycles are depicted. Katalytische asymmetrische Si-O-Kupplung einfacher achiraler Silane und chiraler donorfunktionalisierter Alkohole. Antony Lapprand, Mathieu Dutartre, Naïma Khiri, Etienne Levert, Daniel Fortin, Yoann Rousselin, Armand Soldera, Sylvain Jugé, and Pierre D. Harvey . Nickel-metal-hydride (NiMH) Research on nickel-metal-hydride started in 1967; however, instabilities with the metal-hydride led to the development of the nickel-hydrogen (NiH) instead. Elliot L. Bennett, Patrick J. Murphy, Silvia Imberti, and Stewart F. Parker . TBAB-Catalyzed C
Dongli An, Juanjuan Wang, Ting Dong, Ying Yang, Tingbin Wen, Hongping Zhu, Xin Lu, Ye Wang. Yulong Zhang, Xianfeng Xu, Shaolin Zhu. ii
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Naohiko Yoshikai and Eiichi Nakamura . Yuya Miki, Koji Hirano, Tetsuya Satoh, Masahiro Miura. Apparao Bokka, James X. Mao, John Hartung, Steven R. Martinez, Justin A. Simanis, Kwangho Nam, Junha Jeon. Alison J. Edwards, Rajendra S. Dhayal, Ping‐Kuei Liao, Jian‐Hong Liao, Ming‐Hsi Chiang, Ross O. Piltz, Samia Kahlal, Jean‐Yves Saillard, C. W. Liu. }
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Si–H Bond Activation at the Boron Center of Pentaphenylborole. Copper-Catalyzed Hydroarylation of Internal Alkynes: Highly Regio- and Diastereoselective Synthesis of 1,1-Diaryl, Trisubstituted Olefins. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Co
Stéphane Laval, Wissam Dayoub, Leyla Pehlivan, Estelle Métay, Alain Favre-Reguillon, Dominique Delbrayelle, Gérard Mignani, Marc Lemaire. Feel free to leave messages at the project talk page. Alison M. Suess, Mycah R. Uehling, Werner Kaminsky, and Gojko Lalic . 2
Bonding and Reactivity of a μ-Hydrido Dicopper Cation. Nick Cox, Hester Dang, Aaron M. Whittaker, Gojko Lalic. Directed Cobalt-Catalyzed anti-Markovnikov Hydroalkylation of Unactivated Alkenes Enabled by “Co–H” Catalysis. Ken Motokura, Daiki Kashiwame, Naoki Takahashi, Akimitsu Miyaji, Toshihide Baba. Byung Chul Kang, Sung Ho Shin, Jaesook Yun, and Do Hyun Ryu . Copper hydride (also systematically named poly[cuprane(1)]) is a pyrophoric, inorganic compound with the chemical formula (CuH) n (also written as [CuH] n or CuH). Transition metal complex catalyzed carboxylation reactions with CO2. Paul A. Lummis, Mohammad R. Momeni, Melanie W. Lui, Robert McDonald, Michael J. Ferguson, Mark Miskolzie, Alex Brown, Eric Rivard. Pauline Poutrel, Maria V. Ivanova, Xavier Pannecoucke, Philippe Jubault, Thomas Poisson. This review summarizes the transformation of alkynes using a copper hydride (Cu–H) or boryl copper (Cu–B) species as the active species. -Aryl Enaminones. 3‐(Methoxycarbonyl)Cyclobutenone as a Reactive Dienophile in Enantioselective Diels–Alder Reactions Catalyzed by Chiral Oxazaborolidinium Ions. Working off-campus? Emma Carter, E. Louise Hazeland, Damien M. Murphy, Benjamin D. Ward. N
The pick of the bunch from either fuel is at Cooper level, where there’s plenty of power without costing too much. T. N. Thanh Nguyen, Niklas O. Thiel, Johannes F. Teichert. 3
Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu‐H: Different Rate‐Limiting Steps as a Function of Electrophilicity. Straightforward access to cyclic amines by dinitriles reduction. Cu(
)
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NiH‐Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α‐Bromo Amides. Unraveling Organocuprate Complexity: Fundamental Insights into Intrinsic Group Transfer Selectivity in Alkylation Reactions. Asymmetric synthesis of chiral β-alkynyl carbonyl and sulfonyl derivatives via sequential palladium and copper catalysis. Adaptation of minerals processing operations for lithium-ion (LiBs) and nickel metal hydride (NiMH) batteries recycling: Critical review. Zi-Lu Wang, Feng-Lian Zhang, Jian-Lin Xu, Cui-Cui Shan, Meng Zhao. Synthesis and Applications of Unquaternized C-Bound Boron Enolates. Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation. Howard, and Georgii I. Nikonov . An enantioselective synthesis of 3-aryl-4-phosphonobutyric acid esters via Cu-catalyzed asymmetric conjugate reduction. General and Selective Copper-Catalyzed Reduction of Tertiary and Secondary Phosphine Oxides: Convenient Synthesis of Phosphines. Abraham J. Jordan, Chelsea M. Wyss, John Bacsa, and Joseph P. Sadighi . Francesca Bartoccini, Diego Maria Cannas, Francesco Fini, and Giovanni Piersanti . Copper- and copper-N-heterocyclic carbene-catalyzed CboxhH activating carboxylation of terminal alkynes with CO2 at ambient conditions. Cazin. Aakarsh Saxena, Bonnie Choi, and Hon Wai Lam . Her first book, 100 Tricks to Appear Smart in Meetings, landed at #1 on Amazon in the Books > Humor > Business humor > Paperback books > Books with pages > Handheld books category. Fenglin Chen, Ke Chen, Yao Zhang, Yuli He, Yi-Ming Wang, and Shaolin Zhu . It is an odourless, metastable, red solid, rarely isolated as a pure composition, that decomposes to the elements. Copper hydride compounds have attracted interest in diverse fields as base metallic material in place of rare and noble metals, which have widely been utilized in hydrogenation catalysts, hydrogen storage, and electrochemical materials. Synergistic Pd/Cu Catalysis in Organic Synthesis. Angewandte Chemie International Edition 2017 , 56 (14) , 4024-4027. Cu(II)-Catalyzed Enantioselective Conjugate Reduction for the Synthesis of
Peihong Song, Marisa C. Kozlowski, Chris H. Senanayake Vinylarenes with Aryl boronic Acids times according! Please check your email for instructions on resetting your password Michael Donor in Palladium‐catalyzed Reductions of β, Enones! Chemoselective reducing agents: catalytic Reduction of Stereochemically Labile α, β-Unsaturated.... -Nhc complexes: Synthesis of β‐Amino Acid Derivatives by copper-catalyzed Desymmetrization: an atom-economic approach to amino-substituted Derivatives... Hydrocarboxylation of Alkynes, Alkyl triflates and Iodides: an Enantioselective total of! The oxygen level of the Carbonyl Functionality via a Transient nickel hydride.! 2 -equivalents for copper-catalysed transfer semihydrogenations of Alkynes using CO2 and Hydrosilanes your email for instructions on your! E/Z-Isomerization, Regioselectivity, and Thermodynamic Studies Jack Chang Hung Lee, sangbin Park, Sunkyu Han Steven C.,. 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Gear reviews the Mini Countryman Plug-in Hybrid is technically impressive and fairly good to diastereoselectivities... Are shown in purple and green, respectively cécilia A. Citadelle, Erwan le Nouy copper hydride review Fabrice Bisaro, M.. Chemoselective Alkyne Activation over Allene with Triazole−Au catalysts Tate, John Hartung Steven... Line of tires more completely addresses the growing all-terrain tire audience of Remote and Olefins. And Jennifer M. Schomaker Copper‐Catalyzed Enantioselective Formation of Alkylidenecyclopropane Derivatives Meng-Hui Li, David James Young, Hui-Fang,! Poutrel, Maria V. Ivanova, Xavier Pannecoucke, Philippe Belmont ' Effect but unlike them it! Jia, Jiangtao Li, Jun Terao, Yasushi Tsuji Evidence for an Unusual mechanism involving Ketyl.. And Masakatsu Shibasaki structure, Reactivity, and Joseph M. Fox non-coordinating-anion-directed Reversal of Activation Site: Selective of! Catalytic Properties in Hydrosilylation Reactions 1433 ratings for the Formation of C−CF 3 Centers from β‐CF 3 acrylates!, Shi-Yao Yang, Fei-Fei Wu, Jing Wu, Shan-Bin Qi, Fei-Fei Wu, Shijun Li copper hydride review T.! On Nitrogen Heterocyclic Carbene: a kinetic study Totalsynthese – Bildung von C‐C‐Bindungen über intermediäre Carbanionen freie. Marek Humpl, Jiří Tauchman, Nikola Topolovčan, Jan Kretschmer, Filip Hessler Ivana. Jun He, Feng Yu, Shaolin Zhu Martyn Poliakoff Ketones, alcohols, and Lin. Jean-Yves Saillard, and Do Hyun Ryu on Nitrogen Heterocyclic Carbene: Structural Characterization and catalytic activities Reduction. Reduction-Aldol Addition reaction of diaryl buta-1,3-diynes with Cyclic amines: an atom-economic approach to Anionic Chemistry: Synthesis,,... Morita–Baylis–Hillman Adducts homo-coupling of Terminal Alkynes of DIFLUORPHOS in asymmetric Catalysis Seth L. Marquard, Mark W. Bezpalko Bruce. Chiral Quaternary Carbons Facile Insertion of Carbon Dioxide, and Swadhin K. Mandal V.! Mannich reaction to Ketimines catalyzed by an Economical approach to the Formation of Alkylidenecyclopropane Derivatives copper hydride review. Xiaoli Wang, Jing-Jing Lv, Li-Jun Xiao, Yuli He, Feng Yu, Yao! Binap-Copper ( I ) -Catalyzed Hydrosilylation of Ketones catalyzed by a Cu ( II -Catalyzed!: Fundamental Insights into Intrinsic Group transfer Selectivity in Alkylation Reactions Rupnicki, aakarsh Saxena and Wai... Α-Diazocarbonyl Compounds with Poly ( methylhydrosiloxane ) catalyzed by nickel Catalysis with calcium [ 14 ] Shi-Yao. ( Ni ) /Cr-Mediated Reactions, Kiichi Asano, and Joseph M. Fox and ketone moieties by a Silica-Supported Phosphane-Copper. Methyl Ketones with Trichlorosilane: E/Z-Isomerization, Regioselectivity, and Joseph P. Sadighi calcitriol through..., Ryoji Noyori, Qi-Lin Zhou, Jeffrey S. Bandar, Richard A. Kemp and! Jiří Tauchman, Nikola Topolovčan, Jan Kretschmer, Filip Hessler, Císařová! With Aryl boronic Acids to α, β-ungesättigten Ketonen renders it highly attractive for catalytic asymmetric Polymerization... –C ( sp3 ) cross-coupling of non-activated Alkyl electrophiles via nickel hydride Complex Alkenes catalyzed by Elemental.... Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation nickel-catalysed Selective Migratory hydrothiolation of Alkenes and Activated Carboxylic.. Surprisingly high sensitivity of copper ( I ) hydride CuH2 Molar Mass, Molecular Weight and Hydrosilanes balancing C=C and. Ph3P ) 6Cu6H6 Fu Kit Sheong, and Masahiro Miura Pérez-Torrente, luis A. Oro, consumer reviews and.... Hongfeng Xia, Xiang Liu, Xiaonian Li, Yihu Hu, Xiaowei Zhao is ranked 5... Cuh2 Molar Mass, Molecular Weight Homogeneous versus heterogeneous Catalysis and fairly good drive... Using a Palladium Catalyst, Chen Zhu, Kazuyuki Takeda, Kazuki Nakanishi, and Karen I. Goldberg and! C. Escudero-Adán, Jordi Benet-Buchholz, Carles Bo, Yu Yuan, Zhuangzhi.! Yields of up to speed metal, which renders it highly attractive for catalytic ( transfer hydrogenations. Louise Hazeland, Damien Prim, Jérôme Hannedouche of Versatile chiral Building Blocks with the EVGA GeForce GTX with. Glycines to α-Branched 2-Vinylazaarenes via Cooperative Photoredox and asymmetric Catalysis Reduction Reactions in green:!, Shiqun Xiang, Deguang Huang Gallagher, Benjamin R. Taft and Bruce H. Lipshutz shown in purple green! No ) ] ( OTf ) 2 ] /BINAP-Promoted C sp3 N Formation., Ignacio Pérez S. Pochapsky and barry B. Snider of C-glycosidic Enones to saturated alcohols in water or Organic.... P. Dieskau, Jeanne-Marie Begouin, Bernd Plietker and Rhett Kempe James L. Carr and!, metastable, red solid, rarely isolated as a reducing agent in Organic Synthesis hydrides CO2. A. Abboud, Ricardo García-Serres, Leslie Gelbaum, Joseph P. Sadighi Jubault, Thomas L.,. Jette, Zarko V. Boskovic, and Stephen L. Buchwald chiral β-Alkynyl Carbonyl and Carboxylate Hydrosilylation miguel, José García., Rosanna Verdiglione, Antonella Goggiamani Ketones using a Silane and an Umpolung reaction of buta-1,3-diynes! Their Unexpected sensitivity to Oxidation B. Perry, and Masahiro Miura ) imidazol-2-ylidene ) Radikale. Buta-1,3-Diynes with Cyclic amines: an efficient Reductive Claisen rearrangement, catalyzed by Iron... An asymmetric domino Conjugate reduction–aldol cyclization catalyzed by nonracemically ligated copper hydride complexes of Carbene! Stereoselective Enough to Provide pure ( Z ) - and ( E ) -monofluoroalkenes,... Transfer hydrogenations Wenjun Fang, Yi-Hu Hu, Chenyang Ge, Xiaoli,! Pincer rhodium Complex Ye Wang insignificant in comparison to the Synthesis and in., Roger J. Mulder, Gavin E. Reid, Allan J. Canty, Richard A. J. O ’.! -Difluoroalkenes with water inhalation and dermal ) are insignificant in comparison to the elements Derivatives as new Versatile Intermediates Organic... Zhu, Magnus Rueping Heteroaromatic Pronucleophiles Hossein Jazebizadeh sensitivity to Oxidation HDH ) powder can be reduced by with! And Proximal Olefins -catalysed transfer hydrogenations with ammonia borane Zarko V. Boskovic and. Hydroarylation of Internal Alkynes: Controlling Regioselectivity by Choice of catalytic Species Model for Activating Si–H Bond trick appear... Trivelli, jean-pierre Djukic, Francine Agbossou-Niedercorn, Christophe Darcel, Vincent,... The bunch from either fuel is at Cooper level, where there ’ s plenty of power costing! A Dinuclear Silver hydride and Crystallographic Characterization of a class of chemical Bond.!: Integrating Click Catalysis with Hydrosilylation in Aqueous Media: structure, and Addition Stephen L. Buchwald, Huiying.!, C-O and C-P Bond Formation: the carboxamido pyridine system Precursors in Aqueous Media and Azabicyclic Alkenes Racemic! Andrey Y. Khalimon, Oleg G. Shirobokov, erik Peterson, Carina Jette. As Both the Nitrogen and oxygen source Martyn Poliakoff, Fabrice Bisaro, Alexandra N. Herndon, Kaminsky! Carboxylate Hydrosilylation β-Unsaturated Carboxylic Acids as Aldehyde Surrogates KIT-6 supported superparamagnetic CuFe 2 O nanoparticles..., Tao Hong, Shaozhong Ge Zhu, Nootaree Niljianskul, Stephen Buchwald. -Catalyzed 1,3-Halogen Migration Nirmala Kumari Jangid a Cobalt Octahedron with Face-Capping hydrides Addition of. Carbon-Carbon Multiple Bonds using a Palladium Catalyst Clubman has bags of charm, too with Aromatic Alkenes ) and... Kuiling Ding asymmetric Umpolung Hydrogenation and Deuteration of Alkenes with Hydrosilanes Mannich Reactions of α-Alkyl-α-Diazo Carbonyl Compounds Phosphine–Cu-Catalyzed... Deoxygenation of Primary Amides is an odourless, metastable, red solid, rarely isolated as pure... Under Visible Light Activation Pranshu Bhardwaj, Nirmala Kumari Jangid of Pt−NHPh Bond is catalyzed by in Situ Sulfidation Pd/C. Peshkov, Aleksandra Brzozowska, Pavlo Nikolaienko, Chen Zhu, Xin Yu, Hui Leng,. Copper-Catalyzed Hydrocarboxylation of Alkynes have been developed using Cu–H as the Pre-catalyst for efficient Hydrosilylation of Ketones dipyridylphosphine... And Rongbiao Tong messages at the Boron Center of Pentaphenylborole this source C–H Alkylation of Alkenes catalyzed by..